自然杂志 ›› 2016, Vol. 38 ›› Issue (1): 15-22.doi: 10.3969/j.issn.0253-9608.2016.01.003

• 专题综述 • 上一篇    下一篇

西安汉墓出土漆陶器的科学研究

李强①②,李伟东①②,罗宏杰①③,赵凤燕   

  1. ①古陶瓷科学研究国家文物局重点科研基地,上海 200050;②中国科学院上海硅酸盐研究所,上海 200050; ③上海大学,上海 200444;④西安市文物保护考古研究院,西安 710068
  • 收稿日期:2015-09-30 出版日期:2016-02-25 发布日期:2016-02-23
  • 作者简介:罗宏杰:国家杰出青年科学基金获得者,研究方向:陶瓷粉体制备与古陶瓷科技研究
  • 基金资助:
    国家重点基础研究发展计划( 973计划) ( 2012CB720901)和国家自然科学基金重点项目( 51232008)资助

A scientific study on the lacquered potteries excavated from the Han dynasty tombs in Xi’an

LI Qiang①②,  LI Weidong①②,  LUO Hongjie①③,  ZHAO Fengyan   

  1. ①Key Scientific Research Base of Ancient Ceramics, State Administration for Cultural Heritage, Shanghai 200050, China; ②Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;③Shanghai University, Shanghai 200444, China; ④Xi’an Municipal Institute of Archaeology and Cultural Relics Protection, Xi’an 710068, China
  • Received:2015-09-30 Online:2016-02-25 Published:2016-02-23

摘要:

 采用能量色散X射线荧光(EDXRF)、X射线粉末衍射(XRD)、傅里叶红外光谱(FTIR)及电子探针(EPMA)等手段对陕西西 安市汉墓出土的陶器残片进行了测试分析,结果表明:这批陶器中有北方汉墓鲜有报道的红色彩绘漆陶器,其红色颜料为 较常见的朱砂(HgS)。显微结构研究显示至少存在三种类型的陶器:其一,陶胎上先通体涂绘含高锰和铁化合物的棕黑色陶 衣,其中MnO和FeO的质量分数超过20%,后再施红色彩绘层;其二,陶胎上先涂一层薄漆层后再进行彩绘;其三,先在 陶胎上做底灰层,再刷一层薄漆,然后进行彩绘。漆层中都存在添加骨灰和石英的现象,漆灰层中有添加高铁物质及黏土 的现象,其中FeO的质量分数达22%。研究结果不但扩展了陶器的种类,也为漆陶器的保护提供了科学依据。

关键词: 漆陶, 髹漆工艺, 骨灰, 汉墓

Abstract:  The lacquered pottery wares unearthed from the Han dynasty tombs in Xi’an were analyzed using Energy-Dispersive X-Ray Fluorescence (EDXRF), X-Ray Diffraction (XRD), Fourier Transform Infrared Spectrometer (FTIR) and Electro-Probe Micro-Analyzer (EPMA). The results show that some wares exist lacquered potteries painted with red HgS stain, which were rarely discovered from the Han dynasty tombs in Northern China. The microstructure analysis indicates that there are at least three types of pottery wares. Type 1: the pottery body was applied with a dark brown coating before pained in red color. The coating’s total content of MnO and FeO is higher than 20 wt.%. Type 2: the pottery body was thinly lacquered before being painted in colors. Type 3: the pottery body was applied with a base plaster layer, then thinly lacquered, and finally painted in colors. The additions of bone ash and quartz to lacquer layer are commonly found. High iron mineral and clay have been added to the plaster layer with FeO content higher than 22 wt.%. This study can not only increase the pottery species, but also provide scientific methods for the conservation of lacquered potteries.

Key words:  , lacquered pottery, lacquering technique, bone ash, Han dynasty tomb