自然杂志 ›› 2018, Vol. 40 ›› Issue (2): 79-89.doi: 10.3969/j.issn.0253-9608.2018.02.001

• 特约专稿 •    下一篇

有机光致变色二芳基乙烯染料的发展动态

朱世琴,李萌祺,朱为宏   

  1. ①华东理工大学科技信息研究所,上海 200237;②华东理工大学精细化工研究所,上海 200237
  • 出版日期:2018-04-25 发布日期:2018-04-23
  • 作者简介:朱为宏 通信作者,国家杰出青年科学基金获得者,研究方向: 荧光探针及分子逻辑门;有机光致变色材料;有机太 阳电池敏化染料。

Progress on organic photochromic diarylethene dyes

ZHU Shiqin①, LI Mengqi②, ZHU Weihong②   

  1. ①Institute of Science and Technology Information, East China University of Science and Technology, Shanghai 200237, China; ②Institute of Fine Chemicals, East China University of Science and Technology, Shanghai 200237, China
  • Online:2018-04-25 Published:2018-04-23

摘要:

二芳基乙烯化合物以其优异的热稳定性和抗疲劳度,在光、电、热、化学和生化等技术领域引起了广泛重视和应用,而目前二芳基乙烯型光致变色染料在自身性能以及实际应用领域仍然有较大的提升空间。聚焦近年来二芳基乙烯衍生物在拓展性能和应用领域的发展成果,重点阐述了位阻型烯桥对于二芳基乙烯系列染料性能的提升及其应用领域的拓展的作用。

关键词: 光致变色染料, 二芳基乙烯, 位阻型烯桥, 双稳态, 手性

Abstract:

Diarylethene systems have attracted widely attentions and have been applied in photo, electronic, thermal, chemical, biochemcial and so on, for their excellent thermal stability and fatigue resistance. However, it still remains large room to improve the performance and the practical application areas for diarylethene type photochromic dyes. This article focuses on the progress of diarylethene derivatives in recent years. Furthermore, it illustrates the great effects of steric hindered bridge ethene on the performance
of diarylethene series dyes.