自然杂志 ›› 2023, Vol. 45 ›› Issue (5): 363-370.doi: 10.3969/j.issn.0253-9608.2023.05.005

• 专题综述 • 上一篇    下一篇

拉曼光谱技术在二维半导体光催化剂异质结研究中的应用

吕子轩,崔丹丹†,冯海凤,郝维昌   

  1. 北京航空航天大学 物理学院,北京 100083
  • 收稿日期:2023-07-03 出版日期:2023-10-25 发布日期:2023-10-25
  • 通讯作者: 崔丹丹,研究方向:表面物理与化学、二维材料和光电催化能源转换。
  • 基金资助:
    国家自然科学基金资助项目(52073006)

Application of Raman spectroscopy in the study of heterojunction of two-dimensional semiconductor photocatalysts#br#

LYU Zixuan, CUI Dandan, FENG Haifeng, HAO Weichang   

  1. School of Physics, Beihang University, Beijing 100083, China
  • Received:2023-07-03 Online:2023-10-25 Published:2023-10-25

摘要: 高活性光催化剂的设计是高效利用太阳能的有效手段,其中二维(2D)半导体光催化剂因其独特的物理化学性质,在光催化研究中有着较大优势。构筑异质结具有改变二维半导体能带结构、抑制光生载流子复合等作用,是一种高效的二维半导体光催化剂的设计方法。拉曼光谱技术因其探测时间短、可原位、无损检测以及样品制备简单等优点,在半导体材料研究中的应用逐渐增多。文章介绍了拉曼光谱技术的基本原理,并对近年来二维半导体光催化剂设计的有关研究进行整理,综述了拉曼光谱技术在二维半导体光催化剂异质结研究中的应用,为新型二维半导体光催化剂的设计奠定了技术基础。

关键词: 拉曼光谱技术, 二维半导体光催化剂, 异质结

Abstract: The design of highly active photocatalysts is an effective means of efficient utilization of solar energy, and two-dimensional (2D) semiconductor photocatalysts have great advantages in the study of photocatalysis due to their unique physical and chemical properties. Raman spectroscopy is increasingly used in the research of semiconductor materials because of its advantages such as short detection time, in situ, non-destructive testing and simple sample preparation. In this paper, the basic principle of Raman spectroscopy is introduced, and the research on the design of 2D semiconductor photocatalysts in recent years has been summarized. The application of Raman spectroscopy in the study of transverse and longitudinal heterojunction of 2D semiconductor photocatalysts is reviewed, which lays a technical foundation for the design of new 2D semiconductor photocatalysts.