氮氧化物(NOx )严重威胁人体健康和生态环境。随着火电行业烟气NOx 初步实现超低排放,非电行业烟气NOx 排放控制成为重中之重。NH3 选择性催化还原NOx 是最有效的NOx 控制技术。非电行业烟气含有SO2 、碱性物质以及重金属等杂质,易导致催化剂中毒失活。针对NOx 净化催化剂低温活性不足、SO2 中毒、碱金属中毒以及复合中毒等关键难题,文章综述了各类低温抗中毒NOx 净化催化剂的研究进展,总结了提高催化剂的低温活性、抗SO2 中毒、抗碱金属中毒以及抗复合中毒的策略。文章为开发低温抗中毒NOx 净化催化剂提供了研究思路,为推进NOx 净化催化剂在非电行业烟气NOx 净化中的实际应用提供理论指导。
Nitrogen oxides (NOx) threaten to the human health and ecological environment. As the gradual realization of ultra-low
emission of NOx in thermal power industries, the emission reduction of NOx in non-electrical industries becomes urgent. Selective
catalytic reduction of NOx by NH3 is the most effective NOx control technology. The flue gas of non-electrical industries generally
contains SO2 , alkali and heavy metals that easily lead to the catalyst inactivation. In view of the key problems of NOx reduction
catalysts such as the poor low-temperature activity, SO2 -poisoning, alkali-poisoning, and the multiple poisonings, this paper reviews
the research progress of various low-temperature poisoning-resistant NOx reduction catalysts, and summarizes the strategies for
improving the low-temperature activity, SO2 -resistance, alkali-resistance, and multiple resistance of catalysts. This paper proposes
research strategies for developing low-temperature poisoning-resistant NOx reduction catalysts, and provides imperative guidance for
the practical application of NOx reduction catalyst in non-electrical industries.