纪念上海大学建校百年专刊

非电行业烟气氮氧化物催化净化

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  • 上海大学 理学院化学系,上海 200444

收稿日期: 2022-06-13

  网络出版日期: 2022-08-27

基金资助

国家自然科学基金资助项目(22125604、22106100)、国家重点研发计划课题(2021YFB3500602)

NOx reduction catalysts for non-electrical industries

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  • Department of Chemistry, College of Sciences, Shanghai University, Shanghai 200444, China

Received date: 2022-06-13

  Online published: 2022-08-27

摘要

氮氧化物(NOx )严重威胁人体健康和生态环境。随着火电行业烟气NOx 初步实现超低排放,非电行业烟气NOx 排放控制成为重中之重。NH3 选择性催化还原NOx 是最有效的NOx 控制技术。非电行业烟气含有SO2 、碱性物质以及重金属等杂质,易导致催化剂中毒失活。针对NOx 净化催化剂低温活性不足、SO2 中毒、碱金属中毒以及复合中毒等关键难题,文章综述了各类低温抗中毒NOx 净化催化剂的研究进展,总结了提高催化剂的低温活性、抗SO2 中毒、抗碱金属中毒以及抗复合中毒的策略。文章为开发低温抗中毒NOx 净化催化剂提供了研究思路,为推进NOx 净化催化剂在非电行业烟气NOx 净化中的实际应用提供理论指导。

本文引用格式

韩璐蓬, 张登松 . 非电行业烟气氮氧化物催化净化[J]. 自然杂志, 2022 , 44(4) : 287 -300 . DOI: 10.3969/j.issn.0253-9608.2022.04.004

Abstract

Nitrogen oxides (NOx) threaten to the human health and ecological environment. As the gradual realization of ultra-low
emission of NO in thermal power industries, the emission reduction of NOin non-electrical industries becomes urgent. Selective
catalytic reduction of NOx by NH3 is the most effective NOx  control technology. The flue gas of non-electrical industries generally
contains SO2 , alkali and heavy metals that easily lead to the catalyst inactivation. In view of the key problems of NOx reduction
catalysts such as the poor low-temperature activity, SO2 -poisoning, alkali-poisoning, and the multiple poisonings, this paper reviews
the research progress of various low-temperature poisoning-resistant NOx reduction catalysts, and summarizes the strategies for
improving the low-temperature activity, SO2 -resistance, alkali-resistance, and multiple resistance of catalysts. This paper proposes
research strategies for developing low-temperature poisoning-resistant NOx reduction catalysts, and provides imperative guidance for
the practical application of NOx reduction catalyst in non-electrical industries.
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