中文

Chinese Journal of Nature ›› 2020, Vol. 42 ›› Issue (1): 51-58.doi: 10.3969/j.issn.0253-9608.2020.01.006

• Review Article • Previous Articles     Next Articles

Atomic dispersed metal catalysts derived from metal-organic frameworks

LIU Minmin① , ZHANG Xinquan①② , CHEN Chunhua① , WANG Linlin① , YAN Wei① , ZHANG Jiujun①#br#   

  1. ①Institute for Sustainable Energy/College of Sciences, Shanghai University, Shanghai 200444, China; ②School of Materials of Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
  • Received:2019-07-02 Online:2020-02-15 Published:2020-02-17

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Abstract: In recent years, atomic dispersed metal catalysts (ADMCs) have attracted wide attentions in the field of electrocatalysis due to their maximum atomic utilization efficiency (100%), unique active sites and high catalytic activity, stability and selectivity. Currently, as a prospective supporting material, metal-organic frameworks (MOFs) have been widely used for the preparation of ADMCs due to their specific molecular structure blocks, adjustable functional groups and effective coordination. In this review, the development of ADMCs derived from MOFs and their applications in electrochemical catalytic oxygen reduction reaction (ORR) are discussed. This paper also discussed the important progress of ADMCs made in this area, as well as some of the challenges and opportunities.

Key words: atomic dispersed metal catalyst, metal organic framework, preparation, electrocatalysis, oxygen reduction