诺贝尔奖简介

量子点的发现和创新——诺贝尔化学奖背后的科学精神

展开
  • 北京理工大学 材料学院,北京 100081

收稿日期: 2023-11-21

  网络出版日期: 2023-12-21

The discovery and innovations of quantum dots: Scientific spirit beyond the Nobel Prize in Chemistry

Expand
  • School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China

Received date: 2023-11-21

  Online published: 2023-12-21

摘要

2023年诺贝尔化学奖授予对量子点的发现和合成作出重要贡献的三位科学家:芒吉•G•巴文迪(Moungi G. Bawendi)、路易斯•E•布鲁斯(Louis E. Brus)和阿列克谢•I•叶基莫夫(Alexei I. Ekimov)。文章主要介绍量子点研究开始前后的科学背景、发现过程以及发展过程中的创新历程,特别是以三位科学家为代表的量子点研究者们所表现出的科学精神。

本文引用格式

钟海政, 刘小丽 . 量子点的发现和创新——诺贝尔化学奖背后的科学精神[J]. 自然杂志, 2023 , 45(6) : 417 -422 . DOI: 10.3969/j.issn.0253-9608.2023.06.003

Abstract

2023 Nobel Prize in Chemistry awarded to three scientists for exploring the nanoworld. Moungi G. Bawendi, Louis E. Brus and Alexei I. Ekimov developed and discovered quantum dots, particles whose sizes govern their properties. In this paper, we tried to describe the discovery and innovations of quantum dots as well as the scientific spirit of the researchers during the developments of quantum dots.

参考文献

[1] The Nobel Prize in Chemistry [EB/OL]. [2023-11-10]. https://www.nobelprize.org/prizes/chemistry/.
[2] EFROS A L, BRUS L E. Nanocrystal quantum dots: from discovery to modern development [J]. ACS Nano, 2021, 15(4): 6192-6210.
[3] BAYDA S, ADEEL M, TUCCINARDI T, et al. The history of nanoscience and nanotechnology: from chemical–physical applications to nanomedicine molecules [J]. Molecules, 2020, 25(1): 112.
[4] ROGACH A L. Semiconductor nanocrystal quantum dots synthesis, assembly, spectroscopy and applications [M]. Vienna: Springer,
2008.
[5] MONTANARELLA F, KOVALENKO M V. Three millennia of nanocrystals [J]. ACS Nano, 2022, 16(4): 5085-5102.
[6] LI T, SENESI A J, LEE B. Small angle X-ray scattering for nanoparticle research [J]. Chemical Review, 2016, 116(18): 11128-
11180.
[7] HAGUENAU F, HAWKES P W, HUTCHISON J L, et al. Key events in the history of electron microscopy [J]. Microscopy and
Microanalysis, 2003, 9(2): 96-138.
[8] EKIMOV A I, ONUSHCHENKO A A, TSEKHOMSKI V A. Exciton absorption by copper chloride crystal in glassy matrix [J]. Fiz Khim Stekla, 1980, 6: 511-512.
[9] EKIMOV A I, ONUSHCHENKO A A. Quantum size effect in threedimensional microscopic semiconductor crystals [J]. Soviet Journal
of Experimental and Theoretical Physics Letters, 1981, 34: 345.
[10] GOLUBKOV V V, EKIMOV A I, ONUSHCHENKO A A, et al. Kinetics of CuCl microcrystals growth in a glass matrix [J]. Fiz Khim Stekla, 1981, 7: 397-401.
[11] EKIMOV A I, HACHE F, SCHANNE-KLEIN M C, et al. Absorption and intensity-dependent photoluminescence measurements on CdSe quantum dots: assignment of the first electronic transitions [J]. Journal of the Optical Society of America B, 1993, 10 (1): 100-107.
[12] 约翰•奥顿. 半导体的故事[M]. 北京: 中国科学技术大学出版社, 2015.
[13] FUJISHIMA A, HONDA K. Electrochemical photolysis of water at a semiconductor electrode [J]. Nature, 1972, 238: 37-38.

[14] HENGLEIN A. Small-particle research: physicochemical properties of extremely small colloidal metal and semiconductor particles [J]. Chemical Review, 1989, 89: 1861-1873.

[15] KALYANASUNDARAM K, BORGARELLO E, DUONGHONG D, et al. Cleavage of water by visible-light irradiation of colloidal CdS solutions; inhibition of photocorrosion by RuO2 [J]. Angew Chem Int Ed, 1981, 20(11): 987-988.

[16] BRUS L E. Electron-electron and electron-hole interactions in small semiconductor crystallites: The size dependence of the lowest
excited electronic state [J]. The Journal of Chemical Physics, 1984, 80(9): 4403-4409.
[17] STEIGERWALD M L, BRUS L E. Synthesis, stabilization, and electronic structure of quantum semiconductor nanoclusters [J]. Annual Review of Materials Science, 1989, 19(1): 471-495.
[18] MURRAY C B, Norris D J, BAWENDI M G. Synthesis and characterization of nearly monodisperse CdE (E = sulfur, selenium, tellurium) semiconductor nanocrystallites [J]. Journal of the American Chemical Society, 1993, 115 (19): 8706-8715.
[19] EMPEDOCLES S A, NORRIS D J, BAWENDI M G. Photoluminescence spectroscopy of single CdSe nanocrystallite quantum dots [J]. Phys Rev Lett, 1996, 77: 3873.
[20] NORRIS D J, BAWENDI M G. Measurement and assignment of the size-dependent optical spectrum in CdSe quantum dots [J]. Physical Review B, 1996, 53(24): 16338.

[21] NIRMAL M, DABBOUSI B O, BAWENDI M G, et al. Fluorescence intermittency in single cadmium selenide nanocrystals [J]. Nature, 1996, 383(6603): 802-804.
[22] REED M A, RANDALL J N, AGGARWAL R J, et al. Wetsel observation of discrete electronic states in a zero-dimensional semiconductor nanostructure [J]. Physical Review Letters, 1988, 60: 535-537.
[23] PAUL A A. Semiconductor clusters, nanocrystals, and quantum dots [J]. Science, 1996, 271(5251): 933-937.
[24] REISS P, PROTIÈRE M, LI L. Core/Shell semiconductor nanocrystals [J]. Small, 2009, 5(2): 154-168.
[25] HINES M A, GUYOT-SIONNEST P. Synthesis and characterization of strongly luminescing ZnS-capped CdSe nanocrystals [J]. Journal of Physical Chemistry,1996, 100(2): 468-471.
[26] GARCÍA DE ARQUER F P, TALAPIN D V, KLIMOV V I, et al. Semiconductor quantum dots: technological progress and future
challenges [J]. Science, 2021, 373: 6555.
[27] PENG X G, MANNA L, YANG W D, et al. Shape control of CdSe nanocrystals [J]. Nature, 2000, 404: 59-61.
[28] YU H, LI J B, LOOMIS R A, et al. Cadmium selenide quantum wires and the transition from 3D to 2D confinement [J]. Journal of
the American Chemical Society, 2003, 125(52): 16168-16169.
[29] ITHURRIA S, BOUSQUET G, DUBERTRET B. Continuous transition from 3D to 1D confinement observed during the formation
of CdSe nanoplatelets [J]. Journal of the American Chemical Society, 2011, 133(9): 3070-3077.
[30] PENG X G. An essay on synthetic chemistry of colloidal nanocrystals [J]. Nano Research, 2009, 2(6): 425-447.
[31] MICIC O I, CURTIS C J, JONES K M, et al. Synthesis and American Chemical Society, 2008, 130(49): 16770-16777.

[36] SCHMIDT L C, PERTEGAS A, GONZALEZ-CARRERO S, et al. Nontemplate synthesis of CH3NH3PbBr3 perovskite nanoparticles
[J]. Journal of the American Chemical Society, 2014, 136(3): 850-853.
[37] PROTESESCU L, YAKUMIN S, BODNARCHUK M I, et al. Nanocrystals of cesium lead halide perovskites (CsPbX3, X = Cl, Br,
and I): novel optoelectronic materials showing bright emission with wide color gamut [J]. Nano Letters, 2015, 15(6): 3692-3696.
[38] ZHANG F, ZHONG H Z, CHEN C, et al. Brightly luminescent and color-tunable colloidal CH3NH3PbX3 (X = Br, I, Cl) quantum dots:
potential alternatives for display technology [J]. ACS Nano, 2015, 9(4): 4533-4542.
[39] Alivisatos Lab [EB/OL]. [2023-11-10]. https://alivisatoslab.uchicago.edu/.

文章导航

/