自然杂志 ›› 2011, Vol. 33 ›› Issue (1): 13-18.

• 专题综述 • 上一篇    下一篇

车载储氢技术的发展与挑战*

孙大林   

  1. 教授,复旦大学材料科学系,上海 200433
  • 收稿日期:2010-08-31 修回日期:2010-10-31 出版日期:2011-02-20 发布日期:2011-02-20
  • 基金资助:

    *国家自然科学基金项目(50925102)

Development and Challenge for OnBoard Hydrogen Storage

SUN Da-lin   

  1. Professor, Department of Materials Science, Fudan University, Shanghai 200433, China
  • Received:2010-08-31 Revised:2010-10-31 Online:2011-02-20 Published:2011-02-20

摘要: 研发高效、安全、低成本的车载储氢系统对发展氢燃料电池汽车至关重要,也面临诸多挑战。美国能源部关于车载储氢系统的技术指标不是针对某种特定的储氢方式,而是参照当今使用汽油的轿车性能指标提出的。经过近十年的努力,基于气态、液态和固态的三种车载储氢方式的燃料电池汽车均有许多成功的示范案例。但由于存在不同程度的缺陷与不足,三种储氢方式中尚无一种能同时满足各项指标。高压气态储氢的体积密度偏低,提高压力又会带来安全隐患;液态储氢有自挥发和高成本的问题;基于储氢材料为工作介质的固态储氢尚需研发高性能的轻质储氢材料。笔者评述了国内外在车载储氢技术方面所取得的新成果与新进展。

关键词: 氢气, 车载储氢, 燃料电池汽车, 石墨烯, 硅, 异质结, 光电探测

Abstract: A safe, efficient and lowcost hydrogen storage system is highly demanded for onboard application. The target performance set by the US DOE for hydrogen storage system is not based on any specific medium or technology, but on equivalency to the current gasoline storage system in terms of weight, volume, cost and other operating parameters. Through a decade’s efforts, successful examples have been demonstrated in several prototype fuel cell vehicles in which the hydrogen is supplied by a highpressure hydrogen tank, a liquid hydrogen tank or a tank filled with solidbased hydrogen storage materials. Unfortunately, none of them meets all of the US DOE targets due to some unresolved problems. Gaseous storage suffers from low volumetric density and safety concern, while liquefaction storage is not yet practical because of the boiloff of hydrogen and cost issues. Highperformance hydrogen storage materials for a solidbased storage system are needed to be developed. The new progress made in worldwide on the onboard hydrogen storage is reviewed herein.

Key words: hydrogen, onboard hydrogen storage, fuel cell automobile