自然杂志 ›› 2013, Vol. 35 ›› Issue (1): 47-055.

• 科技进展 • 上一篇    下一篇

有机-无机能源矿产相互作用及其共存成藏(矿)

刘池洋①    毛光周②    邱欣卫③    吴柏林④     赵红格⑤     王建强⑥   

  1. ①教授,④⑤副教授,⑥讲师,西北大学大陆动力学国家重点实验室,西安 710069;
    ②讲师,山东科技大学山东省沉积成矿作用与沉积矿产重点实验室,山东青岛 266590;
    ③博士,中国科学院广州地球化学研究所,广州 510640
  • 收稿日期:2012-08-05 修回日期:2012-09-05 出版日期:2013-02-25 发布日期:2013-02-25
  • 基金资助:

    国家重点基础研究发展规划项目(2003CB214607);国家自然科学基金重点项目(90814005);西北大学大陆动力学国家重点实验室科技部专项经费资助

Organic-inorganic energy minerals interactions and the accumulation and mineralization in the same sedimentary basins

LIU Chi-yang①, MAO Guang-zhou②, QIU Xin-wei③, WU Bo-lin④, ZHAO Hong-ge⑤, WANG Jian-qiang⑥   

  1. ①Professor, ④⑤Associate Professor, ⑥Lecturer, State Key Laboratory of Contiental Dynamics, Northwest University, Xi'an 710069, China; 
    ②Lecturer, Shandong Provincial Key Laboratory of Depositional Mineralization & Sedimentary Minerals, Shandong University of Science and Technology, Qingdao 266590, Shandong Province, China; 
    ③Ph. D., Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
  • Received:2012-08-05 Revised:2012-09-05 Online:2013-02-25 Published:2013-02-25

摘要: 油、气、煤、铀同盆共存富集存在普遍,其形成、分布关联密切;有机-无机相互作用是多种能源矿产共存成藏(矿)的成因机理和联系纽带。有机油、气、煤所提供的强大的吸附作用、还原环境和络合作用等,对无机铀的沉淀、富集和成矿具有重要的积极作用。在烃类生成过程中,无机组分具有重要的催化作用,如铀因其特殊的原子结构,具有独特良好的配位性能,因而具有良好的络合催化及氧化还原催化特性。铀的存在,为生物的繁殖提供能量,使之勃发繁衍,利于优质烃源岩的形成;可导致烃源岩在温度较低阶段液态烃提前生成,并使总烃产量增加;同时在高温阶段可减缓有机质过度成熟,利于所生烃类的保存。铀应为低(未)熟油、气生成的重要因素之一。这种少量烃类的提前生成和运移,可使成岩早期阶段孔渗性能良好的储层较大范围变为亲油性,为后期大规模生成的油气运移和成藏创造了有利条件,使得即使是致密储层也有形成大规模商业油气藏(田)的可能。

关键词: 有机-无机相互作用, 油, 气, 煤, 铀, 多种能源矿产, 地质催化作用, 生烃演化, 还原作用

Abstract: The coexistence and enrichment in the same basin of oil, gas, coal and uranium are universal, and the origin and distribution relative to each other closely. Organic-inorganic interactions is the genetic mechanism and connection link of the multi-energy resources coexistence and mineralize. The strong absorption, reducing environment, complexation  and other functions from organic oil, gas and coal played an important and positive role in accumulating of inorganic uranium. Inorganic component plays an important catalysis in the process of hydrocarbon generation. Uranium has good ligancy due to its special atomic structure, thus it has excellent characteristic of complexing catalysis and oxidation/reduction. Uranium may offer energy to living beings to keep their propagation and vegetation, lead erupting multiply, and favor the formation of high quality source rocks. Uranium can promote the generation of liquid hydrocarbon in advance, increase the total hydrocarbon production of hydrocarbon source rock at lower temperature, meanwhile, it can prevent organic matter from overmature to preserve hydrocarbon produced at high temperature well. Uranium should be one of the inorganic accelerating factors of the hydrocarbon generation. The generation and migration of such a small amount of hydrocarbon can turn the host reservoir with good poroperm characteristics at eogenetic stage into lipophilicity in a wide rage, and it provides advantage conditions for migration and accumulation of late large scale generated hydrocarbons. It is possible that even though the dense reservoir also become a large-scale commercial hydrocarbon reservoir/field.

Key words: organic-inorganic interaction, oil, gas, coal, uranium, multiple energy resources, geology catalysis, hydrocarbon-generation evolution, reduction